Os dejo la relación de extras que contendrán los 23 títulos, las últimas son las que menos llevarán solamente 1 hora de material adicional. Lo pongo en spoiler para quien no le interese.

Additional bonus content in the BOND 50 collection includes cast and crew commentaries, the behind-the-scenes making of each film, in-depth interviews with every actor that played Bond, a closer look at the exotic locations as shot on-the-set, the women of Bond, the villains of Bond, Bond's cars and gadgets, music videos and much, much more.

Spoiler:

DISC TWENTY THREE - Bonus Material

NEW – The World of Bond – the 007 films have a look, style and attitude that is signature Bond. From the cars, to the women, to the villains and even the music, Bond films stand apart. The World of Bond takes the viewer through the best of five decades worth of classic James Bond in one thrilling montage. The World of Bond showcases the fascinating and entertaining interplay among unforgettable moments of danger, seduction, adventure and a dash of that distinguished humor that fans have cherished from the beginning up until now. To add to the experience, The World of Bond featurette will also offer a Pop-Up Trivia option to challenge even the sharpest of fans with little known facts and interesting trivia from the Bond Universe.
NEW – Being Bond – there's only one James Bond – but he's proven too much for only one actor to play the role. In the franchise's 50-year run, six distinguished actors have taken on the part and secured a spot in cinematic history. Sean Connery, George Lazenby, Roger Moore, Timothy Dalton, Pierce Brosnan, and Daniel Craig each reflect on the impact and importance of taking on such a famous role. With this piece, gain insight into what each actor brought to the character and discover how they shaped the world's most timeless secret agent.
SKYFALL Videoblogs – behind-the-scenes look at the making of SKYFALL from the cast and crew

DISC ONE - Dr. No (Over 3 hours of content)

Commentary with Director Terence Young and cast and crew
6 Featurettes
Original Theatrical Trailer, TV and radio spots
Photo Galleries

DISC TWO - From Russia With Love (Over 3 hours of content)

Commentary with Director Terence Young and cast and crew
2 Featurettes
Animated Storyboard Sequence
Original Theatrical Trailer, TV and radio spots
Photo Galleries

DISC THREE - Goldfinger (Over 5 hours of content)

Commentary with Director Guy Hamilton
Commentary with the cast and crew
3 Featurettes
Original Screen Tests with Theodore Bikel and Tito Vandis
Original Theatrical Trailer, TV and radio spots
Original Publicity Featurette
Original Radio Interviews With Sean Connery
Photo Galleries

DISC FOUR - Thunderball (Over 6 hours of content)

Commentary with Director Terence Young
Commentary with Editor Peter Hunt and Screenwriter John Hopkins
4 Featurettes
Original Theatrical Trailer, TV and radio spots
Photo Galleries

DISC FIVE - You Only Live Twice (Over 4 hours of content)

Commentary with Director Lewis Gilbert and cast and crew
4 Featurettes
Animated Storyboard Sequence
Original Theatrical Trailer, TV and radio spots
Photo Galleries

DISC SIX - On Her Majesty's Secret Service (Over 4 hours of content)

Commentary with Director Peter Hunt and cast and crew
4 Featurettes
Original Theatrical Trailer, TV and radio spots
Photo Galleries

DISC SEVEN - Diamonds Are Forever (Over 4 hours of content)

Commentary with Director Guy Hamilton and cast and crew
3 Featurettes
Deleted Scenes
Original Theatrical Trailer, TV and radio spots

DISC EIGHT - Live and Let Die (Over 7 hours of content)

Commentaries with Director Guy Hamilton, Roger Moore and Tom Mankiewicz
3 Featurettes
Original Theatrical Trailer, TV and radio spots
Photo Galleries

DISC NINE - The Man with the Golden Gun (Over 5 hours of content)

Commentary with Director Guy Hamilton and the cast and crew
Commentary with Roger Moore
2 Featurettes
Original Theatrical Trailer, TV and radio spots
Photo Galleries

DISC TEN - The Spy Who Loved Me (Over 5 hours of content)

Commentary with Director Lewis Gilbert and cast and crew
Commentary with Roger Moore
3 Featurettes
Original Theatrical Trailer, TV and radio spots

DISC ELEVEN - Moonraker (Over 5 hours of content)

Commentary with Director Lewis Gilbert and cast and crew
Commentary with Roger Moore
4 Featurettes
Original Theatrical Trailer
Photo Gallery

DISC TWELVE - For Your Eyes Only (Over 7 hours of content)

Commentary with Director John Glen and the cast and crew
Commentary with Roger Moore
Commentary with Producer Michael G. Wilson and crew
4 Featurettes
Animated Storyboard Sequences for Snowmobile Chase & Underwater
Music Video performed by Sheena Easton
Deleted Scenes and Expanded Angles
Original Theatrical Trailer, TV and radio spots
Photo Galleries

DISC THIRTEEN - Octopussy (Over 6 hours of content)

Commentary with Director John Glen
Commentary with Roger Moore
4 Featurettes
Original Screen Tests with James Brolin
"All Time High" Music Video
Original Theatrical Trailers

DISC FOURTEEN - A View to a Kill (Over 6 hours of content)

Commentary with Director John Glen and the cast and crew
Commentary with Roger Moore
4 Featurettes
A View to a Kill Music Video performed by Duran Duran
Original Theatrical Trailers and TV spots

DISC FIFTEEN - The Living Daylights (Over 5 hours of content)

Commentary with Director John Glen and cast and crew
3 Featurettes
Deleted scenes with introductions from Director John Glen
The Living Daylights Music Video performed by A-Ha
Original Theatrical Trailers

DISC SIXTEEN - Licence to Kill (Over 6 hours of content)

Commentary with Director John Glen and cast
Commentary with Producer Michael G. Wilson and crew
3 Featurettes
Licence to Kill Music Video performed by Gladys Knight
"If You Asked Me To" Music Video Performed by Patti LaBelle
Opening Titles Sequence
Original Theatrical Trailers
Photo Galleries

DISC SEVENTEEN - GoldenEye (Over 5 hours of content)

Commentary with Director Martin Campbell and Producer Michael G. Wilson
8 Featurettes
Deleted scenes
GoldenEye Music Video performed by Tina Turner

DISC EIGHTEEN - Tomorrow Never Dies (Over 9 hours of content)

Commentary with Director Roger Spottiswoode and Dan Petrie, Jr.
Commentary with Vic Armstrong and Producer Michael G. Wilson
2 Featurettes
Interview with Composer David Arnold
Deleted and Extended Scenes with introduction from Director Roger Spottiswoode
Tomorrow Never Dies Music Video performed by Sheryl Crow
The James Bond Theme (Moby's Re-Version)

DISC NINETEEN - The World Is Not Enough (Over 6 hours of content)

Commentary with Director Michael Apted
Commentary with Peter Lamont, David Arnold and Vic Armstrong
4 Featurettes
Opening Titles Sequence
The World Is Not Enough Music Video performed by Garbage
Deleted, Extended and Alternate Scene
Original Theatrical Trailer
Photo Galleries

DISC TWENTY - Die Another Day (Over 8 hours of content)

Commentary with Director Lee Tamahori and Producer Michael G. Wilson
Commentary with Pierce Brosnan and Rosamund Pike
5 Featurettes
MI6 Datastream Trivia Track with Branching Video
Opening Titles Sequence
Photo Galleries

DISC TWENTY ONE - Casino Royale (Over 1 hour of content)

Becoming Bond
James Bond: For Real
Chris Cornell Music Video

DISC TWENTY TWO - Quantum of Solace (Over 1 hour of content)

2 Featurettes
"Another Way to Die" Music Video
Original Theatrical Trailers